I have an iPOD mini library and now have a IPhone 4S.  I updated my library and synced my phone to the library but can not figure out how to get the music library to download to my  iphone

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I have an iPod mini library which I have update. I now have an iPhone 4S which I have synced to the library using a MS XP computer. I can not figure out how to get the library to download to my iPhone?
Thanks,  This caused me to go back and try again since the solution seemed so simple.  What I did was when it started downloading, it started with the iphones apps to my computer.  I did not want the apps downloaded on my computer so I stopped it.  If I would have waited, the music was uploaded right after the apps were downloaded.
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